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71.
International organizations sometimes institutionalize country groupings by specifying differentiated commitments that may, in turn, affect negotiation dynamics. Drawing on incentive-based and socialization arguments, we develop a “constructed peer group” hypothesis suggesting that by creating these groups those organizations may actually construct new lines of confrontation over and above the substance-based disagreements existing between countries. This generates a particular type of path dependence, rendering broad-based international agreements more difficult in the future.We analyze this question at the example of the United Nations Framework Convention on Climate Change's increasingly politicized split between Annex I and non-Annex I countries. Using a self-coded dataset of country oral statements during the negotiations between December 2007 and December 2009 we assess whether Annex I membership influences a country's stance toward other countries’ arguments, while controlling for country characteristics that may drive their preferences and the affiliation to Annex I. We find that the split between Annex I and non-Annex I has indeed influenced negotiation behavior and amplified the divide between developing and industrialized countries in the climate negotiations. 相似文献
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Isabel Pôças João Gonçalves Bruno Marcos Joaquim Alonso Pedro Castro João P. Honrado 《International journal of geographical information science》2014,28(11):2356-2371
This article proposes and illustrates a practical methodological framework to evaluate the fitness for use of spatial data sets for environmental and ecological applications, focusing on user requirements for specified application contexts. The methodology is based on the use of metadata to analyze similarity between the data characteristics and the user’s needs or expectations for several quality indicators. Additionally, the concept of ‘critical factors’ is introduced in this framework, allowing users to define which quality indicators have greater importance given their own requirements or expectations and the specified application contexts. The proposed methodology further allows integrating and interconnecting the spatial data quality (SDQ) evaluation methodology with metadata geoportals in WebGIS platforms, facilitating its operation by users from non-spatial disciplines and with often limited expertise on this subject. Examples of the evaluation of fitness for use for specific application contexts within the project BIO_SOS (‘Biodiversity Multi-SOurce Monitoring System: From Space To Species’ FP7 project) are presented. By providing a prompt and straightforward evaluation tool, the proposed methodology can encourage the implementation of SDQ evaluation routines in ecological assessment and monitoring programs, promoting a more adequate use of geospatial data and ultimately contributing to well-supported policy and management decisions. 相似文献
75.
表面张力是固体表面重要的物理化学参数之一,其大小与温度和界面两相物质的性质有关。基于Young方程的推导,使用接触角测量法计算固体表面张力已被广泛应用于表面科学和工程领域。宝玉石材料大多具有光洁的表面,在接触角测量的准确性方面较其他表面不均一的固体材料具有明显的技术优势。本文运用现代仪器(FTA200动态接触角测量仪)测量了15个天然和合成宝玉石品种(钻石、合成碳硅石、合成立方氧化锆、碧玺、托帕石、翡翠、琥珀等),以及经覆膜和充填2种处理方法的宝玉石样品(镀膜钻石、覆膜托帕石、覆膜翡翠、覆膜琥珀、充填碧玺)的表面接触角,并运用公式计算其表面张力。测试数据表明,不同品种宝玉石的接触角数值存在差异,如钻石的接触角值为56.68°,其仿制品立方氧化锆的接触角值为37.79°;覆膜处理与未经覆膜处理的天然宝玉石的接触角数值差异明显,如琥珀的接触角值为92.49°,覆膜琥珀的接触角值为66.49°;充填处理宝玉石接触角的测试由于控制液滴的大小受条件限制操作难度较大,测试结果不能准确表达为裂隙中充填物的接触角数值,故充填处理的宝石不宜采用此方法进行区分。研究表明,对于部分宝玉石品种和覆膜处理宝玉石,其表面接触角及表面张力数值差异显著,可以作为宝玉石品种的辅助鉴定依据;尤其是运用接触角的差异对于宝玉石鉴定具有较好的判别性,能够对不同品种的天然宝玉石与表面覆膜的宝玉石样品进行有效区分。与常规宝石检测方法(如红外光谱、折射率测量方法)对比,接触角测量方法具有测量准确、操作简便,不破坏样品的特点,符合宝玉石无损鉴定的基本原则,且能够安全快速地测量高折射率宝石,可以解决宝玉石表面覆膜等与表面物性相关的检测疑难问题。 相似文献
76.
The La Peña alkaline complex (LPC) of Miocene age (18–19 Ma) lies on the eastern front of the Precordillera (32°41ʹ34ʺS, 68°59ʹ48″W, 1400–2900 m a.s.l.), 30 km northwest of Mendoza city, Argentina. It is a subcircular massif of 19 km2 and 5 km in diameter, intruded in the metasedimentary sequence of the Villavicencio Formation of Silurian-Devonian age. It is the result of integration of multiple pulses derived from one or more deep magma chambers, which form a suite of silicate rocks grouped into: a clinopyroxenite body, a central syenite facies with a large breccia zone at the contact with the clinopyroxenite, bodies of malignite, trachyte and syenite porphyry necks, and a system of radial and annular dikes of different compositions. Its subcircular geometry and dike system distribution are frequent features of intraplate plutons or plutons emplaced in post-orogenic settings. These morphostructural features characterize numerous alkaline complexes worldwide and denote the importance of magmatic pressures that cause doming with radial and annular fracturing, in a brittle country rock. However, in the LPC, the attitude of the internal fabric of plutonic and subvolcanic units and the preferential layout of dikes match the NW–SE extensional fractures widely distributed in the host rock. This feature indicates a strong tectonic control linked to the structure that facilitate space for emplacement, corresponding to the brittle shear zone parallel to the N–S stratigraphy of the country rock. Shearing produced a system of discontinuities, with a K fractal fracture pattern, given by the combination of Riedel (R), anti-Riedel (R′), (P) and extensional (T) fracture systems, responsible for the control of melt migration by the opening of various fracture branches, but particularly through the NW–SE (T) fractures. Five different pulses would have ascent, (1) an initial one from which cumulate clinopyroxenite was formed, (2) a phase of mafic composition represented by dikes cross-cutting the clinopyroxenite, (3) a malignite facies that causes a small breccia in the clinopyroxenite, (4) a central syenite facies that develops breccias at the contact with the clinopyroxenite and, finally, (5) porphyry necks and a system of radial dikes intruding all units. At the moment of the emplacement different mechanisms would have acted, they summarized in: 1) opening of discontinuities synchronous to the magma circulation as the principal mechanism for formation of dikes and conduits; 2) stoping processes, that play an important role in the development of the breccia zone and enabling an efficient transference of material during the emplacement of the syenitic magma and 3) shear-related deformation (regional stress), affected the internal fabric of the facies, causing intracrystalline deformation and submagmatic flow, which is very evident in the central syenite intrusive. The kinematic analysis of shear planes allows proposing that emplacement of the LPC took place in a transtensive regime, which would have occurred in the back-arc of the Andes orogen, during a long period spanning from Miocene to the present, of the compressive deformation responsible, westward and at the same latitude, for the development of the Aconcagua fold and thrust belt. 相似文献
77.
依托珠江流域某冲填土场地工程实例,介绍了真空预压法的施工参数及应用效果,另对“薄弱部位”泥浆搅拌桩密封墙处地层的强度进行了定量分析,结果表明真空预压法适用于此类场地,加固效果明显,但密封墙位置强度降幅较大,需采取换填等措施二次处理后才能使用,可为其他类似工程提供参考经验. 相似文献
78.
通过对大同市某变电站下伏采空区治理的实例,介绍了采空区治理方法的选择和实施过程,探讨了采空区注浆加固治理工程设计理念,总结了施工过程中各种问题的解决方法和成功经验。 相似文献
79.
在适当的热处理条件下,黄绿色绿柱石能够转变为理想颜色的海蓝宝石。天然海蓝宝石与热处理海蓝宝石的价格差异较大,因此探索热处理海蓝宝石的诊断性鉴定特征就显得十分必要。对不同温度下热处理海蓝宝石进行傅里叶变换红外光谱和激光拉曼光谱的测试分析,结果发现,当热处理温度超过400℃后,随着加热温度的升高,在红外光谱中由[Fe2(OH)4]2+伸缩振动gI起的3233cm叫处吸收谱峰明显减弱,直至消失。5268cm叫附近由水伸缩和弯曲振动}I起合频区的吸收带由尖峰变得宽缓;8700,6818cm叫两处水吸收峰的相对强度也随着加热温度升高而减弱。热处理海蓝宝石Si-0-Si伸缩振动产生的在682,3604cm叫处的拉曼光谱谱峰强度随着加热温度升高逐渐减弱,1070cm“处的拉曼峰强度明显降低。经700℃加热后,拉曼光谱基线明显向上方漂移。这些光谱特征变化对热处理海蓝宝石的鉴定有重要意义。 相似文献
80.
海北化工厂已停产15年之久,但Cr6+污染依旧十分严重.调查得知,海北化工厂原生产废液排放及堆存废渣经降水淋滤作用下渗,是造成该区包气带和地下水Cr6+污染的主要原因.采用地下水质量法和污染指数法评价分析该区地下水Cr6+污染范围和污染影响程度.评价结果显示:Cr6+重度污染区面积0.75 km2,厂区包气带Cr6+平均含量67.67×10-6,平均超标指数1691.75,地下水中Cr6+浓度超过Ⅴ类水标准.在分析厂区周边水文地质条件的基础上,提出清除场地废渣废料并置换被污染的包气带、采用抽水法治理被污染的地下水的综合方案. 相似文献